Vol. 9 Issue 2 Apr.-Jun. 2018

Development of Water Stress Indices for the Watersheds of Thailand to Support Water Footprint Calculations

Shabbir H. Gheewala*, Thapat Silalertruksa, Pariyapat Nilsalab, Naruetep Lecksiwilai, Wanchat Sawaengsak, Rattanawan Mungkung and Jirawat Ganasut

<div style="text-align:justify;"><strong><span style="font-size:medium;line-height:115%;font-family:Verdana, Geneva, sans-serif;background-color:#ffffff;color:#000000;">Abstract: </span></strong><span style="font-size:medium;line-height:115%;font-family:Verdana, Geneva, sans-serif;background-color:#ffffff;color:#000000;">When demands for water cannot be met sufficiently due to lack of available water, the excess demand will possibly cause impacts on freshwater resources. Thus, water footprint (WF) and water stress index (WSI) are gaining recognition as important tools for assessing water use impact leading to support policy makers on development of water resource management policy. The WSI has been widely applied as a characterization factor of water scarcity footprint; a first attempt was made some years ago by determining the WSI for 25 watersheds of Thailand based on a top-down approach. Subsequently, in this study, a bottom-up approach with more refined data was used to determine the annual and monthly WSIs for the 25 watersheds. The most critical watersheds were found to be located in the Central region of Thailand. Cultivating in irrigated or non-irrigated areas and shifting crop calendar can affect the WSI values. Accordingly, the annual and monthly WSI would be recommended as one of the criteria or tools to support the future agricultural policy decision making in various applications, particularly agricultural zoning. The annual WSI may be useful for the top-down vision for a quick assessment and the monthly WSI for a comprehensive assessment.</span></div>

Catalytic Non-oxidative Dehydrogenation of Ethanol into Acetaldehyde and Hydrogen using Monometallic Cu, Ag and Bimetallic Cu-Ag Catalysts Supported by SiO2

Pornlada Daorattanachai*, Sansanee Totong and Navadol Laosiripojana

<p style="margin-bottom:0cm;margin-bottom:.0001pt;text-align:justify;line-height:normal;"><strong><span style="font-size:medium;font-family:Verdana, Geneva, sans-serif;">Abstract</span></strong><strong><span style="font-size:medium;font-family:Verdana, Geneva, sans-serif;">:</span></strong><span style="font-size:medium;font-family:Verdana, Geneva, sans-serif;">&nbsp;The purpose of this work was to investigate catalytic non-oxidative&nbsp;dehydrogenation&nbsp;of ethanol into acetaldehyde and hydrogen using monometallic&nbsp;Cu, Ag and bimetallic Cu-Ag </span><span style="font-size:9.0pt;font-family:'Times New Roman',serif;"><span style="font-family:Verdana, Geneva, sans-serif;"><span style="font-size:medium;">catalysts supported on SiO<sub>2</sub> at metal loading variations (2.5, 5, and 10 wt.%). The experimental results revealed that Cu catalysts with low Cu loading (2.5-5 wt.%) exhibited better activity than Ag catalysts</span></span><span style="color:red;font-family:Verdana, Geneva, sans-serif;font-size:medium;">&nbsp;</span><span style="font-family:Verdana, Geneva, sans-serif;font-size:medium;">in temperature range of 250-400&deg;C. </span></span><span style="font-size:medium;font-family:Verdana, Geneva, sans-serif;">Moreover, we found that the addition of Cu </span><span style="font-size:9.0pt;font-family:'Times New Roman',serif;"><span style="font-family:Verdana, Geneva, sans-serif;"><span style="font-size:medium;">considerably promoted the catalytic dehydrogenation activity of Ag/SiO<sub>2</sub> catalysts. Among all prepared catalysts, the 10 wt.% Cu-Ag/SiO<sub>2</sub> showed the best catalytic activity for non-oxidative dehydrogenation of ethanol with ethanol conversion of 53%, acetaldehyde yield of 42%, and hydrogen yield of 49% at 400&deg;C.</span></span></span></p><span style="font-family:Verdana, Geneva, sans-serif;font-size:medium;"></span><p style="margin-bottom:0cm;margin-bottom:.0001pt;text-align:justify;line-height:normal;"><span style="font-size:medium;font-family:Verdana, Geneva, sans-serif;">&nbsp;</span></p><span style="font-family:Verdana, Geneva, sans-serif;font-size:medium;"></span><strong><span style="font-size:medium;line-height:115%;font-family:Verdana, Geneva, sans-serif;">Keywords: </span></strong><span style="font-size:medium;line-height:115%;font-family:Verdana, Geneva, sans-serif;">Dehydrogenation; Ethanol; Acetaldehyde; Hydrogen; Cu; Ag; Cu-Ag.</span>